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An orthorhombic α-Pr2WO6 (PrWO) polymorph with a = 16.57(5) Å, b = 5.52(5) Å, and c = 8.73(1) Å, isostructural to α-La2WO6 and α-Nd2WO6, has been stabilized in the form of thin film by pulsed laser deposition on (001)-or...